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Synlett 1998; 1998(5): 473-474
DOI: 10.1055/s-1998-1704
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Tandem Cycloaddition-Cyclopentannulation Processes of 2-Aminobuta-1,3-dienes and Fischer Alkynylcarbene Complexes as a Tool for the Preparation of Complex Polycyclic Scaffolds

José Barluenga* , Fernando Aznar, Sofía Barluenga, Alfredo Martín, Santiago García-Granda, Eduardo Martín
  • *Instituto Universitario de Química Organometálica "Enrique Moles"-Unidad Asociada al C.S.I.C.; Fax 34 8 5 10 34 46; E-mail: barluenga@sauron.quimica,uniovi.es
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Publication Date:
31 December 2000 (online)

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This letter describes a convenient one-pot four-step cascade reaction of 2-aminodienes and vinyl substituted alkynyl carbene complexes that produces complex polycyclic molecules in a stereoselective manner.

2-aminodienes - carbene complex - cycloaddition - cyclopentannulation - tandem