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Synlett 1998; 1998(3): 286-288
DOI: 10.1055/s-1998-1639
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Synthetic Use of 1-(p-Toluenesulfonyloxy)-1,2-benziodoxol-3(1H)-one: Iodination of Aromatic Rings

Takahito Muraki* , Hideo Togo, Masataka Yokoyama
  • *Department of Chemistry, Faculty of Science, Chiba University, Yayoi-cho 1-33, Inage-ku, Chiba 263, Japan; Fax 0 43-2 90-28 74; E-mail: octogo@science.s.chiba-u.ac.jp
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Publikationsdatum:
31. Dezember 2000 (online)

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Treatment of various aromatic compounds with 1-(p-toluenesulfonyloxy)-1,2-benziodoxol-3(1H)-one 1A and iodine gave the corresponding iodinated compounds in good yields. Similarly, chlorination and bromination proceeded effectively. As compared with other trivalent iodine compounds, the iodinane 1A showed the best reactivity as a halogenation reagent.

1-(p-toluenesulfonyloxy)-1,2-benziodoxol-3(1H)-one - iodination - aryl iodide