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Synlett 1998; 1998(2): 177-179
DOI: 10.1055/s-1998-1600
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Synthesis of Phosphonate Analogues of 2-Deoxyribose-1-Phosphate

María-José Rubira* , María-Jesús Pérez-Pérez, Jan Balzarini, María-José Camarasa
  • *Instituto de Química Médica (C.S.I.C.), Juan de la Cierva 3, 28006 Madrid, Spain; Fax [int] +34-1-5 64 48 53; E-mail: mjesus@pinar1.csic.es
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Publikationsdatum:
31. Dezember 2000 (online)

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Phosphonate derivatives of 2-deoxyribose have been synthesized for the first time, by Lewis acid-mediated reaction of glycosyl donors with diisopropylhydroxymethylphosphonate for compounds 2 or with triisopropyl phosphite for compounds 3. Although, the selectivity of the reaction was moderate, in both cases the α-glycosides were predominantly obtained.

2-deoxyribose - phosphonates - α-glycosides