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Synlett 1998; 1998(2): 153-156
DOI: 10.1055/s-1998-1588
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1,3-Dipolar Cycloaddition Reactions of 4-Silacyclohex(hept)-2-en-1-one Derivatives: Synthesis of Novel Azasilabicyclic Compounds

D. Damour* , M. Barreau, V. Fardin, F. Dhaleine, M. Vuilhorgne, S. Mignani
  • *Rhône-Poulenc Rorer S. A. Centre de Recherche de Vitry-Alfortville, 13 Quai Jules Guesde-BP 14, 94403, Vitry-sur-Seine Cedex, France; Fax 33 1 55 71 81 29
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Publication Date:
31 December 2000 (online)

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[3 + 2] Cycloaddition reactions of N-benzyl-azomethine ylide with 4-silacyclohex(hept)-2-en-1-ones provides novel 3-aza-1-silabicyclo[3.4.0]hexanes and 3-aza-1-silabicyclo[3.5.0]heptanes.

1,3-dipolar cycloaddition - 4-silacyclohex(hept)-2-en-1-ones - 3-aza-1-silabicyclo[3.4.0]hexanes - 3-aza-1-silabicyclo[3.5.0]heptanes - N-n-buthoxymethyl-N-trimethyl-silylmethylbenzylamine