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Synlett 1997; 1997(1): 117-118
DOI: 10.1055/s-1997-717
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Stereoselective Hydrogenation of Tetrasubstituted Enones

Masahiko Yamaguchi* , Aiko Nitta, Ravinder S. Reddy, Masahiro Hirama
  • *Department of Chemistry, Graduate School of Science, Tohoku University, Aoba, Sendai 980-77, Japan
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Publication Date:
22 March 2004 (online)

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Contigous tertiary asymmetric centers were constructed stereoselectively by cis-hydrogenation of tetrasubstituted (E)-enones using Rh/alumina catalyst.

Rh/alumina - tetrasubstituted enone - cis-hydrogenation - contiguous asymmetric centers