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Synlett 1997; 1997(SI): 505-507
DOI: 10.1055/s-1997-6140
DOI: 10.1055/s-1997-6140
letter
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Original Synthesis of 1,2-Oxathiolan-2-oxides and Vinyl Cyclopropane Carboxylic Esters
Further Information
Publication History
Publication Date:
31 December 2000 (online)
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1,2-Oxathiolan-2-oxides or vinyl cyclopropane carboxylic esters are prepared chemoselectively and in rather good yields from methyl 2,4-pentadienoate, tributylstannyllithium and carbonyl compounds. The later are formally deoxygenated in the process and play the role of carbenes.
allylstannane - vinyl cyclopropane - 1,2-oxathiolan-2-oxide - cyclopropanation - substitution