Download PDF
Synlett 1997; 1997(SI): 505-507
DOI: 10.1055/s-1997-6140
letter
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.

Original Synthesis of 1,2-Oxathiolan-2-oxides and Vinyl Cyclopropane Carboxylic Esters

Alain Krief* , Laurent Provins
  • *Department of Chemistry, Facultés Universitaires Notre-Dame de la Paix, 61 rue de Bruxelles, B-5000 Namur, Belgium
Further Information

Publication History

Publication Date:
31 December 2000 (online)

  PDF Download  Permissions and Reprints All articles of this category

1,2-Oxathiolan-2-oxides or vinyl cyclopropane carboxylic esters are prepared chemoselectively and in rather good yields from methyl 2,4-pentadienoate, tributylstannyllithium and carbonyl compounds. The later are formally deoxygenated in the process and play the role of carbenes.

allylstannane - vinyl cyclopropane - 1,2-oxathiolan-2-oxide - cyclopropanation - substitution