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Synlett 1997; 1997(6): 701-703
DOI: 10.1055/s-1997-3267
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Highly Efficient and Convenient Methods for the Direct Conversion of Aryl Silyl Ethers and Aryl Acetates into Aryl Alkyl Ethers

Takeshi Oriyama* , Kojiro Noda, Kaori Yatabe
  • *Department of Chemistry, Faculty of Science, Ibaraki University, Bunkyo, Mito 310, Japan
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Publication Date:
31 December 2000 (online)

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Direct conversion of aryl trialkylsilyl ethers and aryl acetates into the corresponding alkyl-protected phenols such as benzyl and allyl ethers can be conveniently performed by the reaction with alkyl halide in the presence of cesium fluoride and sodium methoxide, respectively, in a one-pot procedure.

aryl silyl ethers - aryl acetates - aryl alkyl ethers - cesium fluoride - sodium methoxide