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Synlett 1997; 1997(6): 659-660
DOI: 10.1055/s-1997-3252
DOI: 10.1055/s-1997-3252
letter
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Addition of Organolithiums to the (R)-O-(1-Phenylbutyl)hydroxylamine (ROPHy) Oxime of Cinnamaldehyde. Asymmetric Synthesis of α-Aminoacids
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Publication History
Publication Date:
31 December 2000 (online)
A new asymmetric synthesis of α-aminoacids is described in which the key step is the diastereoselective addition of organolithium reagents to (R)-O-(1-phenylbutyl) cinnamaldoxime.
oxime ether - diastereoselective addition - hydroxylamine - aminoacid