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Synlett 1997; 1997(6): 710-712
DOI: 10.1055/s-1997-3243
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Synthesis of 4,7-Disubstituted Phenanthrolines as Key Building Blocks for the First Preparation of Macrocyclic Mono- and Bisphenanthrolines with exo-Coordination Sites

Michael Schmittel* , Andrea Ganz
  • *Institut für Organische Chemie der Universität Würzburg, Am Hubland, D-97074 Würzburg, Germany, FAX: Int +49 931 888 4606, e-mail: mjls@chemie.uni-wuerzburg.de
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Publication Date:
31 December 2000 (online)

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The preparation of various 4,7-bisalkynylated phenanthrolines and 4,7-bis(4-hydroxyphenoxy)phenanthroline as well as their use in the synthesis of the first macrocyclic phenanthrolines and bisphenanthrolines with exo-coordination sites is described.

phenanthroline - bisphenanthroline - macrocyclization - Heck reaction

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