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Synthesis 1997; 1997(9): 1045-1048
DOI: 10.1055/s-1997-1302
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A Short Efficient Synthesis of 11-Monoacetate of Drimane-8α,11-diol from Norambreinolide

Kaleria I. Kuchkova*
  • *Institutul de Chimie al Academiei de ŞtiinŢe a Republicii Moldova, strada Academiei 3, MD 20 28 Chişinău, Moldova
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Publikationsdatum:
31. Dezember 2000 (online)

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An efficient two-step synthesis of 11-acetoxydrimane-8α-ol, a valuable intermediate for the synthesis of naturally occurring drimanes, from commercially available norambreinolide, is described. The Baeyer-Villiger oxidation of the initially obtained 8α-hydroxy-12-oxo-11-homodrimane is considered as the key step.

oxidation