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Synthesis 1997; 1997(5): 533-535
DOI: 10.1055/s-1997-1225
DOI: 10.1055/s-1997-1225
short paper
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Direct and Selective N-Monoalkynylation and N-Monoalkenylation of Anilines with Alky(e)nyl Methanesulfonates Using Methylmagnesium Bromide as a Base
Further Information
Publication History
Publication Date:
31 December 2000 (online)
![](https://www.thieme-connect.de/media/synthesis/199705/lookinside/thumbnails/10.1055-s-1997-1225-1.jpg)
Several anilines were directly N-monoalkynylated and N-monoalkenylated with alkynyl methanesulfonates and alkenyl methanesulfonates, respectively, using methylmagnesium bromide as a base in good yields with high selectivities.
anilines - monoalkynylation - monoalkenylation - magnesium complex - methanesulfonates