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Synlett 1997; 1997(12): 1456-1458
DOI: 10.1055/s-1997-1067
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Benzylic and Allylic Amination

Yoshinori Kohmura, Ken-ichi Kawasaki, Tsutomu Katsuki*
  • *Department of Chemistry, Faculty of Science, Kyushu University 33, Hakozaki, Higashi-ku, Fukuoka 812-81, Japan, Fax +81 92 642 2607
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Publication History

Publication Date:
31 December 2000 (online)

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N-(p-Toluenesulfonyl)amino group can be directly introduced at allylic or benzylic carbon by treating alkenes or alkylarenes with t-butyl N-(p-toluenesulfonyl)peroxycarbamate in the presence of Cu(II) triflate.

benzylic amination - allylic amination - t-butyl N-(p-toluene-sulfonyl)peroxycarbamate - copper(II) triflate

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