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Synlett 1997; 1997(11): 1257-1258
DOI: 10.1055/s-1997-1018
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Heterogeneous Enantioselective Catalytic Reduction of Ketones

R. ter Halle, E. Schulz, M. Lemaire*
  • *Institut de Recherches sur la Catalyse, Laboratoire de Catalyse et Synthèse Organique, Université C. Bernard, CPE, Bât. 308, 43 Bd du 11 novembre 1918, 69622 Villeurbanne Cedex, France
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Publication Date:
31 December 2000 (online)

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(1S,2S)-N-(styrene-p-sulfonyl)-1,2-dipenylethylenediamine was copolymerized with styrene and divinylbenzene to give functionalized polymers. These polymers were shown to be good ligands in the iridium and ruthenium catalyzed hydride transfer reduction (HTR) of acetophenone. However, reutilization of these heterogeneous catalysts proved to be difficult.

iridium - ruthenium - catalysis - reduction - polymers

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