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Synlett 1997; 1997(11): 1309-1311
DOI: 10.1055/s-1997-1011
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Allylation of Aldehydes with Allyltin Compounds in Acidic Aqueous Media-A Catalytic Version

Akira Yanagisawa, Miwa Morodome, Hiroshi Nakashima, Hisashi Yamamoto*
  • *Graduate School of Engineering, Nagoya University, Chikusa, Nagoya 464-01, Japan
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Publication Date:
31 December 2000 (online)

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Allylation reaction of aldehydes with allyltributyltin was achieved using Sn catalysts in acidic aqueous media. Exclusive aldehyde selectivity was observed for competitive reactions of aldehydes and ketones with allyltributyltin in the presence of 5 mol% of tetraallyltin or SnCl4 in a mixture of aqueous HCl solution and THF.

catalytic allylation - allyltributyltin - aldehyde - Sn catalyst - acidic aqueous media

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