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Synlett 1996; 1996(12): 1159-1161
DOI: 10.1055/s-1996-5714
DOI: 10.1055/s-1996-5714
letter
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A Versatile A-ring Synthesis for Taxol
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Publikationsverlauf
Publikationsdatum:
31. Dezember 2000 (online)
Careful A-ring substructure analysis for taxol has been carried out and a practical synthesis to all emergent substructures, viable as A-ring building blocks, has been developed. The synthesis starts from 2-methyl-1,3-cyclohexanedione and enters via ketalized trimethylvinyltriflate and ketalized trimethylester to trimethylketoalcohol(s) with the hydroxyl group protected.
taxanes - palladium - methoxycarbonylation