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Synlett 1996; 1996(9): 890-892
DOI: 10.1055/s-1996-5586
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Radical-Induced Cyclizations of 1-Sila-cyclopent-2-ene Derivatives: Synthesis of Novel Azasilabicyclic Compounds

Dominique Damour, Michel Barreau, Fabrice Dhaleine, Gilles Doerflinger, Marc Vuilhorgne, Serge Mignani*
  • *Rhône-Poulenc Rorer S.A. Centre de Recherche de Vitry-Alfortville, 13 Quai Jules Guesde-BP 14, 94403, Vitry-sur-Seine Cedex, France, Fax 33 (1) 45 73 81 29
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Publication Date:
31 December 2000 (online)

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A radical-induced cyclization reaction on the vinylsilane moiety of 1-sila-cyclopent-2-ene derivatives provides a route to novel fused silolano-pyrroles, -pyrrolidinones, -quinoline and -isoquinoline derivatives.

radical-induced cyclizations - 1-sila-cyclopent-2-ene derivatives - azasilabicyclic compounds - vinylsilane moiety