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Synlett 1996; 1996(7): 679-681
DOI: 10.1055/s-1996-5559
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Synthesis of the Carbon Skeleton of the Herbicidins via a Temporary Silaketal Tether

Antony J. Fairbanks, Elisabeth Perrin, Pierre Sinay*
  • *Ecole Normale Supérieure, Département de Chimie, associé au CNRS, 24 rue Lhomond, 75231 Paris Cedex 05, France
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Publication Date:
31 December 2000 (online)

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The carbon skeleton of the herbicidins was constructed by intramolecular radical cyclisation of the selenoglycoside 6 onto the temporarily tethered exomethylene furanose 5.

herbicidins - silaketal tether - C-disaccharide - radical cyclisation