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Synlett 1996; 1996(8): 720-722
DOI: 10.1055/s-1996-5517
DOI: 10.1055/s-1996-5517
letter
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.
Aluminum Tris(4-bromo-2,6-diphenylphenoxide) (ATPH-Br): an Effective Catalyst for Claisen Rearrangement
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Publikationsverlauf
Publikationsdatum:
31. Dezember 2000 (online)
![](https://www.thieme-connect.de/media/synlett/199608/lookinside/thumbnails/10.1055-s-1996-5517-1.jpg)
A new Lewis acidic receptor, aluminum tris(4-bromo-2,6-diphenylphenoxide)(ATPH-Br), is a powerful promoter of the Claisen rearrangement of various allyl vinyl ethers and is effective for controlling the stereochemistry of the resulting rearrangement products.
Lewis Acidic Receptor - ATPH-Br - Claisen Rearrangement - Stereoselectivity