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Synlett 1996; 1996(6): 555-556
DOI: 10.1055/s-1996-5501
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Allylstannylation of Alkenes via Radical Process1

Katsukiyo Miura, Toshie Matsuda, Takeshi Hondo, Hajime Ito, Akira Hosomi*
  • *Department of Chemistry, University of Tsukuba, Tsukuba, Ibaraki 305, Japan, Fax (+81) 298 53 6503; E-mail: hosomi@staff.chem.tsukuba.ac.jp
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Publication Date:
31 December 2000 (online)

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Allylstannanes bearing an electron-withdrawing group at the β-position easily reacted with various electron-deficient alkenes to introduce both allyl and stannyl groups.

Allylstannylation - β-Substituted Allylstannane - Radical Addition - β-Stannylester - Homoenolate