Download PDF
Synlett 1996; 1996(4): 339-340
DOI: 10.1055/s-1996-5415
letter
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.

C-O versus C-C Tandem Cycloalkylation of Stabilized Carbanions. Facile One-Pot Stereoselective Preparation of Functionalized Cyclic Enol Ethers

Tania Lavoisier, Jean Rodriguez*
  • *Laboratoire RéSo, Réactivité en Synthèse Organique, URA au CNRS 1411, Centre de St-Jérôme, boîte D12, 13397 Marseille cedex 20, France
Further Information

Publication History

Publication Date:
31 December 2000 (online)

  PDF Download  Permissions and Reprints All articles of this category

α,α’-Diactivated ketones 1, 5-8 undergo a facile stereoselective tandem C-O-cycloalkylation process with trans-1,4-dibromo-2-butene 9 leading to synthetically valuable functionalized enol ethers 10-17.

Tandem C-O-cycloalkylation - cyclic enol ethers - stabilized carbanions

      >