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Synlett 1996; 1996(1): 67-68
DOI: 10.1055/s-1996-5318
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A Methodology for Spirocyclopentannulation. Stereoselective Total Synthesis of (±)-Tochuinyl Acetate and (±)-Dihydrotochuinyl Acetate

A. Srikrishna* , T. Jagadeeswar Reddy, P. Praveen Kumar, D. Vijaykumar
  • *Department of Organic Chemistry, Indian Institute of Science, Bangalore - 560 012, India
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Publikationsdatum:
31. Dezember 2000 (online)

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A methodology based on Claisen rearrangement and Wacker oxidation for the spirocyclopentannulation of ketones, and its application to a highly stereoselective first total synthesis of dihydrotochuinyl acetate (8) is described.

Spiro compounds - Claisen rearrangement - Wacker oxidation - Quaternary carbon atoms - Tochuinyl acetates