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Synthesis 1996; 1996(3): 372-376
DOI: 10.1055/s-1996-4220
DOI: 10.1055/s-1996-4220
paper
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A Unique Synthetic Method for Pyridine-Ring Containing Ter-, Quater- and Quinquearyl and Vinylogues by Thermolysis of 2,2-Dichlorocyclopropylmethyleneamines
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Publication History
Publication Date:
31 December 2000 (online)
Teraryls, quateraryls, and quinquearyls composed of a pyridine ring in the segment and their vinylogues were prepared directly by thermal rearrangement of N-(hetero)arylmethyl-2,2-dichloro-1-substituted phenylcyclopropylmethyleneamines in modest to good yields.
dichlorocyclopropylaldimine - thermal rearrangement - arylpyridine - oligoaryl - liquid crystal