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Synlett 1995; 1995(SI): 516-518
DOI: 10.1055/s-1995-5293
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The Pinene Approach to Taxanes 2: Development of a Versatile C9, C10 Linker

Paul A. Wender* , Timothy E. Glass
  • *Department of Chemistry, Stanford University, Stanford, CA 94305, USA, FAX 415-725-0259; Internet: wenderp@leland.stanford.edu
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Publikationsdatum:
31. Dezember 2000 (online)

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A triply convergent approach to the taxane ring system is described which circumvents a previously encoutered limitation of the verbenone photorearrangement and features a novel alkenyl carbanion intermediate.

taxol - vinyl bromide - verbenone