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Synlett 1995; 1995(SI): 513-515
DOI: 10.1055/s-1995-5270
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A New Approach to a Dynemicin A Analogue by Using an Intramolecular Diels-Alder Reaction

Yasuharu Sakamoto, Takashi Takahashi*
  • *Department of Chemical Engineering, Tokyo Institute of Technology, Ookayama, Meguro-ku, Tokyo 152, JAPAN, Fax +81(3)5734-2884; E-mail ttakashi@cc.titech.ac.jp
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Publication Date:
31 December 2000 (online)

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New synthetic approach to the dynemicin skeleton by using an intramolecular Diels-Alder reaction and its diastereoselectivity based on an ”MM2 transition-state model” are described.

dynemicin A - intramolecular Diels-Alder reaction - MM2 transition-state model - [2,3]-Wittig rearrangement - Pd(0)-coupling reaction