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Synlett 1995; 1995(7): 781-784
DOI: 10.1055/s-1995-5052
DOI: 10.1055/s-1995-5052
letter
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Tuning the Reactivity of Glycosides: Efficient One-pot Oligosaccharide Synthesis1
Further Information
Publication History
Publication Date:
31 December 2000 (online)
![](https://www.thieme-connect.de/media/synlett/199507/lookinside/thumbnails/10.1055-s-1995-5052-1.jpg)
Tuning the reactivity of glycosyl donors by selective introduction of different protecting and leaving groups enabled highly efficient oligosaccharide synthesis. Utilising both phenylseleno and ethylthio glycosides in combination with the cyclohexane-1,2-diacetal (CDA) protecting group provided four different levels of reactivity. One-pot sequential glycosidation of three components gave trisaccharides and tetrasaccharides.
Reactivity tuning - cyclohexane-1,2-diacetals (CDA) - one-pot synthesis - oligosaccharides