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Synlett 1995; 1995(7): 681-686
DOI: 10.1055/s-1995-5043
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Novel Bonding Modes in Monomeric and Dimeric Palladium and Platinum Complexes with Cyclopentadienyl Ligands

Gordon K. Anderson*
  • *Department of Chemistry, University of Missouri-St. Louis, 8001 Natural Bridge Road, St. Louis, Missouri 63121, USA, Fax 314-516-5342; E-mail GAnderson@umsl.edu
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Publikationsdatum:
31. Dezember 2000 (online)

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Cyclopentadienyl complexes of palladium and platinum undergo rearrangements from η5 to η1 coordination modes, and, in certain cases, displacement of the cyclopentadienide anion. This reactivity is carried over to diplatinum systems bridged by diphenylphosphinocyclopentadienyl ligands, where the ligand can adopt a range of bonding modes to accommodate the presence or absence of a metal-metal bond.

palladium - platinum - cyclopentadienyls - phosphinocyclopentadienyls - fluxionality