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Synlett 1995; 1995(4): 353-354
DOI: 10.1055/s-1995-4952
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Thermal Ring-opening of 2-bromo- and 2-bromomethyl-substituted phosphiranes

Ngoc Hoa Tran Huy, François Mathey*
  • *Laboratoire ”Hétéroéléments et Coordination”, URA CNRS 1499, DCPH, Ecole Polytechnique, 91128 Palaiseau Cedex, France
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Publication Date:
31 December 2000 (online)

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Terminal phosphinidene complexes [R-P-W(CO)5] (R=Me, Ph) insert into the C-Br bond of vinyl and allyl bromides via intermediate 2-bromo and 2-bromomethylphosphiranes.

phosphiranes - bromovinyl phosphines - phosphinidenes - tungsten pentacarbonyl complexes