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Synlett 1995; 1995(2): 133-141
DOI: 10.1055/s-1995-4882
DOI: 10.1055/s-1995-4882
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Amino Acid Esters: Versatile Chiral Auxiliary Groups for the Asymmetric Synthesis of Nitrogen Heterocycles
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Publikationsverlauf
Publikationsdatum:
31. Dezember 2000 (online)
![](https://www.thieme-connect.de/media/synlett/199502/lookinside/thumbnails/10.1055-s-1995-4882-1.jpg)
The development of amino acid esters as chiral auxiliary groups for the asymmetric construction of N-heterocycles by means of aza Diels-Alder reactions, Mannich reactions, Pictet-Spengler reactions and 1,3-dipolar cycloadditions is described. Also their application in the steric steering of carbo Diels-Alder reactions, radicalic transformations and enantioselective nucleophilic additions to carbonyl groups is highlighted.
Amino acid esters - nitrogen heterocycles - heterocycles - asymmetric synthesis - chiral auxiliary groups