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Synlett 1995; 1995(1): 29-31
DOI: 10.1055/s-1995-4878
DOI: 10.1055/s-1995-4878
letter
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Asymmetric Addition Reaction to Non-Prochiral Carbonyl Compound: Asymmetric Catalytic Formaldehyde-Ene Reaction for Isocarbacyclin Synthesis
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Publication History
Publication Date:
31 December 2000 (online)
![](https://www.thieme-connect.de/media/synlett/199501/lookinside/thumbnails/10.1055-s-1995-4878-1.jpg)
Asymmetric catalysis of ene-type carbonyl addition to achiral/non-prochiral formaldehyde with the homotopic faces is described to provide a new route to the asymmetric synthesis of isocarbacyclin and 3-oxa analogues.
formaldehyde - carbonyl-ene reaction - asymmetric catalyst - double asymmetric induction - isocarbacyclins