Synthesis 1995; 1995(12): 1529-1533
DOI: 10.1055/s-1995-4134
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2-Hydroxy-2,2-dimethylacetic Acid Ester Derived Heterobiaryl Ethers Containing 1,3,5-Triazine Substituents

José Barluenga* , Carlos del Pozo, Bernardo Olano
  • *Instituto Universitario de Química Organometálica ”Enrique Moles”, Unidad Asociada al C.S.I.C., Universidad de Oviedo, Julián Clavería 8, E-33071 Oviedo, Spain, Fax +34(85)103446
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Publikationsverlauf

Publikationsdatum:
31. Dezember 2000 (online)

The 1,3,5-triazines 3 were obtained from methyl 4-formylbenzoate (4) in a multistep synthesis by first introducing the ester unit under Williamson conditions. Subsequently, the 1,3,5-triazine ring was synthesized by reaction of isocyanates with 1,3-diazadienes obtained from N-silylimines.