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Synthesis 1995; 1995(12): 1529-1533
DOI: 10.1055/s-1995-4134
DOI: 10.1055/s-1995-4134
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2-Hydroxy-2,2-dimethylacetic Acid Ester Derived Heterobiaryl Ethers Containing 1,3,5-Triazine Substituents
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Publikationsverlauf
Publikationsdatum:
31. Dezember 2000 (online)
The 1,3,5-triazines 3 were obtained from methyl 4-formylbenzoate (4) in a multistep synthesis by first introducing the ester unit under Williamson conditions. Subsequently, the 1,3,5-triazine ring was synthesized by reaction of isocyanates with 1,3-diazadienes obtained from N-silylimines.
2-hydroxy-2,2-dimethylacetic acid ester derived heterobiaryl ethers - 1,3,5-triazines - 1,3-diazadienes