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Synthesis 1995; 1995(4): 376-378
DOI: 10.1055/s-1995-3928
short paper
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A Simple and Convenient Synthesis of Alkyl Azides under Mild Conditions

Masato Ito, Ken-ichi Koyakumaru, Tetsuo Ohta, Hidemasa Takaya*
  • *Division of Material Chemistry, Graduate School of Engineering, Kyoto University, Sakyo-ku, Kyoto 606-01, Japan, Fax +81(75)7618846
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Publikationsdatum:
31. Dezember 2000 (online)

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Various primary and secondary alkyl azides have been synthesized in high yields by the fluoride anion induced SN2 substitution reactions of the corresponding alkyl halides, phosphates, or tosylates and trimethylsilyl azide.

trimethylsilyl azide - tetrabutylammonium fluoride - alkyl halides - alkyl azides - stereospecific substitution