Synthesis 1994; 1994(10): 1079-1082
DOI: 10.1055/s-1994-25641
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Crosslinking 2,5-Dihydro-1H-pyrrol-1-yloxyl Spin-Label Reagents Bifunctionalized with Azidophthalimidyl and Methylthiosulfonyloxy Groups

Tamás Kálai* , Blanka Rozsnyai, Gyula Jerkovich, Kálmán Hideg
  • *Central Laboratory, Chemistry, University of Pécs, H-7643 Pécs, P. O. Box 99, Hungary
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Publikationsverlauf

Publikationsdatum:
27. September 2002 (online)

Oxy-Cope and ortho ester Claisen rearrangements of 5- and 6-membered N-oxyl radicals were carried out. The resulting more stable 5-membered bromo derivative 6 was used in the synthesis of bifunctionalized crosslinking photo- and thiol-label 12.

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