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Synlett 1994; 1994(7): 537-538
DOI: 10.1055/s-1994-22920
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Regio- and Stereoselective Palladium(0) Catalysed Hydrostannation of Disubstituted Propargyl Alcohols

Nicholas Greeves* , Julie S. Torode
  • *Robert Robinson Laboratories, Department of Chemistry, University of Liverpool, P.O. Box 147, LIVERPOOL, L69 3BX, U.K.
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Publication Date:
18 September 2002 (online)

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Palladium(0) catalysed hydrostannation of disubstituted propargyl alcohols 2 results in formation of the corresponding (E)-ß-vinyl stannanes 4 in good yield with a high degree of regioselectivity when tri-o-toly]phosphine is used as ligand.