Subscribe to RSS
Please copy the URL and add it into your RSS Feed Reader.
https://www.thieme-connect.de/rss/thieme/en/10.1055-s-00000083.xml
Synlett 1994; 1994(3): 191-193
DOI: 10.1055/s-1994-22790
DOI: 10.1055/s-1994-22790
letter
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.
Sequential Heck and Diels-Alder Reactions: Facile Construction of Bicyclic Systems in a Single Synthetic Operation
Further Information
Publication History
Publication Date:
22 March 2002 (online)
![](https://www.thieme-connect.de/media/synlett/199403/lookinside/thumbnails/10.1055-s-1994-22790-1.jpg)
Under catalytic conditions, (3.5 mol% Pd(OAc)2, 1.2 equiv. Ag2CO3 in acetonitrile) 2-bromo-1,6-diene 6 furnishes bis (exomethylene)cyclopentane 7. When generated in the presence of a dienophile, 7 immediately undergoes a Diels-Alder reaction; [4+2]-cycloadducts of 7 were thus prepared with a variety of dienophiles in a one-pot procedure in high yields.