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Synlett 1993; 1993(10): 759-760
DOI: 10.1055/s-1993-22599
DOI: 10.1055/s-1993-22599
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© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.
Copper Mediated Lithium Aluminum Hydride Reduction of Substituted Allylic Epoxides
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Publikationsverlauf
Publikationsdatum:
19. März 2002 (online)
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Copper-mediated lithium aluminum hydride reduction of 1-oxaspiro[2.5]oct-4-enes has been observed to primarily yield 1,4-products, although 1,2-products and general decomposition are encountered. Olefin substitution (α and β) affects the yield and selectivity. Alternate hydride coordination sites redirect reductive opening of these allylic epoxides.