Download PDF
Synlett 1993; 1993(1): 25-26
DOI: 10.1055/s-1993-22333
letter
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.

Silica Gel Catalyzed Addition of Benzenethiol to α,β-Epoxyalkylsilanes and Epoxides

Piotr Raubo* , Jerzy Wicha
  • *Institute of Organic Chemistry, Polish Academy of Sciences, ul. Kasprzaka 44, 01-224 Warsaw, Poland
Further Information

Publication History

Publication Date:
19 March 2002 (online)

 PDF Download  Permissions and Reprints All articles of this category

(Trimethylsilyl)oxiranes react with benzenethiol in the presence of silica gel to give regioselectively α-adducts. Triphenylsilyl ethylene oxide in reaction with benzenethiol and silica gel affords a mixture of α and ß-adducts in a 6:1 ratio. Silica gel - catalyzed addition of benzenethiol is applied also to the representative all-carbon oxiranes.