Subscribe to RSS
Please copy the URL and add it into your RSS Feed Reader.
https://www.thieme-connect.de/rss/thieme/en/10.1055-s-00000084.xml
Synthesis 1992; 1992(1/2): 58-62
DOI: 10.1055/s-1992-34164
DOI: 10.1055/s-1992-34164
paper
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.
Concave Dyestuffs: A Triply Bridged Triphenylmethyl Dication
Further Information
Publication History
Publication Date:
18 September 2002 (online)
A triply bridged triphenylmethyl dication {6,13,23,30,39,46-hexaoxaoctacyclo[16.16. 16.22,5.214,17.219,22.231,34. 235,38.247,50]dohexaconta-2,4,14,16,19,21,31,33,35,37,47, 49,51,53,55,57,59,61-octadecaene-8,10,25,27,41,43-hexayne-1,18-diyliumbis (tetrafluoroborate) 4} and its open-chained analogue 1,6-bis{4-[bis-(4-methoxyphenyl) methyl]phenoxy}hexa-2,4-diynediylium bis(tetrafluoroborate) (9) are synthesized by using a new variant of the Eglinton reaction. Compound 4 constitutes the first example of concave dyestuffs bearing a large rigid cavity.