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Synthesis 1992; 1992(1/2): 211-214
DOI: 10.1055/s-1992-34149
DOI: 10.1055/s-1992-34149
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Easy Procedures for the Synthesis of Soluble [2,3,9,10,16,17,23,24-Octakis(pentyloxy)phthalocyaninato]ruthenium(II) and (Phthalocyaninato)ruthenium(II)
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Publikationsverlauf
Publikationsdatum:
18. September 2002 (online)
The first synthesis of a pure, soluble substituted (phthalocyaninato)ruthenium(II), (C5H11O)8PcRu (4) by reaction of the corresponding metal-free phthalocyanine (C5H11O)8 PcH2 (3) with RuCl3 · xH2O in 2-ethoxyethanol is described. Also a new synthetic route for the unsubstituted (phthalocyaninato)ruthenium(II), PcRu (7) via the bisquinoline complex 9 is reported.