Easy Procedures for the Synthesis of Soluble [2,3,9,10,16,17,23,24-Octakis(pentyloxy)phthalocyaninato]ruthenium(II) and (Phthalocyaninato)ruthenium(II)

Michael Hanack; José Osío-Barcina; Elisabeth Witke; Jörg Pohmer

doi:10.1055/s-1992-34149

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Synthesis 1992; 1992(1/2): 211-214
DOI: 10.1055/s-1992-34149

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Easy Procedures for the Synthesis of Soluble [2,3,9,10,16,17,23,24-Octakis(pentyloxy)phthalocyaninato]ruthenium(II) and (Phthalocyaninato)ruthenium(II)

Michael Hanack^* , José Osío-Barcina, Elisabeth Witke, Jörg Pohmer

^*Institut für Organische Chemie, Lehrstuhl für Organische Chemie II der Universität Tübingen, Auf der Morgenstelle 18, D-7400 Tübingen 1, Germany

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Publication Date:
18 September 2002 (online)

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The first synthesis of a pure, soluble substituted (phthalocyaninato)ruthenium(II), (C₅H₁₁O)₈PcRu (4) by reaction of the corresponding metal-free phthalocyanine (C₅H₁₁O)₈ PcH₂ (3) with RuCl₃ · xH₂O in 2-ethoxyethanol is described. Also a new synthetic route for the unsubstituted (phthalocyaninato)ruthenium(II), PcRu (7) via the bisquinoline complex 9 is reported.