Subscribe to RSS
Please copy the URL and add it into your RSS Feed Reader.
https://www.thieme-connect.de/rss/thieme/en/10.1055-s-00000084.xml
Synthesis 1992; 1992(11): 1090-1092
DOI: 10.1055/s-1992-26311
DOI: 10.1055/s-1992-26311
short paper
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.
Aluminum Chloride/Dichloromethane (Chloroform) Induced Carbonylation, Ritter Reaction, and Cyanation of Adamantane
Further Information
Publication History
Publication Date:
17 September 2002 (online)
![](https://www.thieme-connect.de/media/synthesis/199211/lookinside/thumbnails/10.1055-s-1992-26311-1.jpg)
The aluminum chloride induced carbonylation, Ritter reaction, and cyanation of adamantane in dichloromethane (chloroform) are reported. The mechanism of the reactions is discussed involving initial hydride abstraction from adamantane by or complexes (indicated by formation of chloromethane or dichloromethane) and subsequent reaction of the 1-adamantyl cation with carbon monoxide, nitriles or cyanotrimethylsilane.