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Synthesis 1992; 1992(11): 1068-1070
DOI: 10.1055/s-1992-26302
short paper
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Synthesis and Glycosidation Reactions of 3-Halo-2,3,6-trideoxy-L-arabino-hexopyranoses

Sofia Mitaku* , Alexios-Léandros Skaltsounis, François Tillequin, Michel Koch
  • *Laboratoire de Pharmacognosie, U. R. A. au C. N. R. S. no 1310, Faculté de Pharmacie, 4 Avenue de l'Observatoire, F-75006 Paris, France
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Publication Date:
17 September 2002 (online)

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Reaction of hydrogen chloride or hydrogen bromide in glacial acetic acid with 3,4-di-O-acetyl-L-rhamnal followed by hydrolysis and acetylation of the reaction product afforded 3-chloro- or 3-bromo-2, 3,6-trideoxy-L-arabino-hexopyranoses. These novel halosugars were further converted into various glycosides.