Download PDF
Synlett 1992; 1992(5): 419-421
DOI: 10.1055/s-1992-21366
letter
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.

Addition of Nitrogen Functionality to Exocyclic Alkenes: A New Procedure for Azidoselenenylation

Robert M. Giuliano* , Franco Duarte
  • *Department of Chemistry, Villanova University, Villanova, Pennsylvania 19085, USA
Further Information

Publication History

Publication Date:
08 March 2002 (online)

  PDF Download  Permissions and Reprints All articles of this category

The reaction of exocyclic alkenes with N-phenylselenophthalimide and azidotrimethylsilane in dichloromethane affords ß-phenylselno azides. Products resulting from the elimination of either the azido or phenylseleno group are not observed under these conditions. Anti-Markovnikov regioselectivity is enhanced by the addition of tetrabutylammonium fluoride to the reaction.

      >