Download PDF
Synthesis 1991; 1991(2): 147-149
DOI: 10.1055/s-1991-26400
paper
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.

Palladium-Catalyzed Hetero-Cope Rearrangement of Alkyl Allyl N-Aryldithiocarbonimidates

J. Garin* , E. Meléndez, F. L. Merchán, T. Tejero, S. Uriel, J. Ayestarán
  • *Departamento de Quimica Orgánica, Instituto de Ciencia de Materiales de Aragón, Universidad de Zaragoza-CSIC, E-50009 Zaragoza, Spain
Further Information

Publication History

Publication Date:
27 September 2002 (online)

  PDF Download  Permissions and Reprints All articles of this category

Palladium-catalyzed [3,3] sigmatropic rearrangement of allyl methyl N-aryldithiocarbonimidates affords methyl N-allyl-N-aryldithiocarbamates. Very high yields of rearranged products can be obtained depending on the substitution pattern of the allyl group.