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Synlett 1991; 1991(8): 593-595
DOI: 10.1055/s-1991-20810
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Synthesis of Glycopeptides with Partial Structure of Human Glycophorin Using the Fluorenylmethoxycarbonyl/ Allyl Ester Protecting Group Combination

Marita Ciommer* , Horst Kunz
  • *Institut für Organische Chemie, Universität Mainz, J. -J. Becherweg 18-20, D-6500 Mainz, Germany
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Publication Date:
07 March 2002 (online)

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Glycopeptide partial structures of glycophorin A are synthesized with Tn antigen type monosaccharide and T antigen type disaccharide side chains O-glycosidically linked to serine or threonine. The N-terminal 9-fluorenylmethoxycarbonyl (Fmoc) group and the C-terminal allyl ester were used as orthogonally stable, selectively removable protecting groups.

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