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Synlett 1991; 1991(6): 428-430
DOI: 10.1055/s-1991-20752
DOI: 10.1055/s-1991-20752
letter
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.
Transition Metal-Diene Complexes in Organic Synthesis; Part 8.1 Iron-Mediated Approach to the Discorhabdin and Prianosin Alkaloids
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Publikationsverlauf
Publikationsdatum:
07. März 2002 (online)
![](https://www.thieme-connect.de/media/synlett/199106/lookinside/thumbnails/10.1055-s-1991-20752-1.jpg)
The iron-mediated spiroannelation of a 6-aminoindo-line derivative (1-acetyl-6-amino-4,7-dimethoxyindoline) allows an easy access to a tetracyclic subunit (tricarbonylspiro[(η4-4-methoxy-2,4- cyclohexadiene) -1,5′ - (1′- acetyl -2′ ,3′ ,5′ ,6′ ,7′ ,8′ - hexahydro- 4′ ,9′ -dimethoxy[1H]pyrrolo[3,2-g]quinoline)]iron) of the discorhabdin and prianosin alkaloids.