PDF herunterladen
Synlett 1991; 1991(3): 155-156
DOI: 10.1055/s-1991-20660
letter
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.

Allylsilanes by the Regio- and Stereocontrolled Substitution of Metalated Homoallylsilanes

A. Degl'Innocenti* , A. Mordini, L. Pagliai, A. Ricci
  • *Centro CNR sulla Struttura dei Composti Eterociclici e loro Applicazione, c/o Dipartimento di Chimica Organica U. Schiff, via G. Capponi 9, I-50121 Firenze, Italy
Weitere Informationen

Publikationsverlauf

Publikationsdatum:
07. März 2002 (online)

  als PDF herunterladen  Lizenzen und Reprints Alle Artikel dieser Rubrik

The metalation of homoallylsilane 1 (4-trimethylsilyl-1-butene) with butyllithium/potassium tert-butoxide followed by quenching with electrophiles (7 examples) leads under mild conditions and with satisfactory yield to a series of 3-substituted allylsilanes [(Z)-2-alkenyltrimethylsilanes].