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Synthesis 1990; 1990(3): 246-248
DOI: 10.1055/s-1990-26844
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Palladium(II)-Catalyzed Cyclopropanation of Simple Allyloxy and Allylamino Compounds and of 1-Oxy-1,3-butadienes with Diazomethane

Yu. V. Tomilov* , A. B. Kostitsyn, E. V. Shulishov, O. M. Nefedov
  • *N. D.Zelinsky Institute of Organic Chemistry Academy of Sciences USSR, Leninsky prospect 47, Moscow B-334, USSR
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Publication Date:
17 September 2002 (online)

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(Alkoxymethyl)-, (aminomethyl)-, (2-alkoxyethenyl)-, (2-acetoxyethenyl)-, and (2-siloxyethenyl)cyclopropanes are obtained in high yields by reaction of allyl alcohol or derivatives, allylamines, 1-alkoxy-, 1-acetoxy-, and 1-trimethylsiloxy-1,3-butadienes with diazomethane in dichloromethane/diethyl ether in the presence of bis(benzonitrile)palladium dichloride.