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Synlett 1990; 1990(9): 551-553
DOI: 10.1055/s-1990-21164
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Synthesis of 2-Alkylthio- and 2-Phenylthio-1-Pyrrolines through the Free Radical Cyclization of Alkenylisonitriles

Mario D. Bachi* , Daniel G. Lasanow
  • *Department of Organic Chemistry, The Weizmann Institute of Science, Rehovot 76100, Israel
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Publication Date:
08 March 2002 (online)

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Cyclic alkylthio- and arylthioimidates (ethyl 2-alkylthio(arylthio)-1-pyrroline-5-carboxylates) are effectively synthesized from ethyl 2-isocyanoalkenoates and primary thiols through the intramolecular addition of carbon-centered alkylthio- and arylthioimidoyl radicals to suitably positioned double bonds.

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