RSS-Feed abonnieren
Bitte kopieren Sie die angezeigte URL und fügen sie dann in Ihren RSS-Reader ein.
https://www.thieme-connect.de/rss/thieme/de/10.1055-s-00000083.xml
Synlett 1990; 1990(6): 347-348
DOI: 10.1055/s-1990-21089
DOI: 10.1055/s-1990-21089
letter
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.
Radical Mediated Oxidations in Organic Chemistry; 2. The Direct Preparation of Esters from Aldehydes
Weitere Informationen
Publikationsverlauf
Publikationsdatum:
08. März 2002 (online)
![](https://www.thieme-connect.de/media/synlett/199006/lookinside/thumbnails/10.1055-s-1990-21089-1.jpg)
Mechanistic investigations of the N-bromosuccinimide oxidation of trimethylsilyl ethers (preceding paper) catalyzed by 2,2′-azobisisobutyronitrile are described. Based on the proposed mechanism, a highly efficient and versatile preparation of mixed esters from aliphatic and aromatic aldehydes and aliphatic trimethylsilyl ethers has been discovered. Aromatic aldehydes require the presence of a catalytic amount of trimethylsilyl triflate to give the mixed esters directly.