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Synlett 1989; 1989(1): 57-59
DOI: 10.1055/s-1989-34710
DOI: 10.1055/s-1989-34710
letter
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.
Selective Oxidation of a Highly-Substituted η4-Cyclopentadiene Cobalt Complex: Partitioning Between Uncomplexed Diene and Cobalticinium Cation Products
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Publikationsverlauf
Publikationsdatum:
26. Februar 2002 (online)
![](https://www.thieme-connect.de/media/synlett/198901/lookinside/thumbnails/10.1055-s-1989-34710-1.jpg)
Simple variation of oxidizing agent (iron nitrate or ferricinuim tetrafluoroborate in acetonitrile) results in selective conversion of a highly substituted η4-cyclopentadiene cobalt complex to either the uncomplexed cyclopentadiene ligand or to the corresponding cationic η5-cyclopentadienyl cobalt complex.